Synthesis and characterisation of quinoline functionalised imidazolium salts
نویسندگان
چکیده
منابع مشابه
Synthesis and Characterisation of Quinoline Functionalised Imidazolium Salts
A series of quinoline based imidazolium salts were prepared and characterised as nucleophilic heterocyclic carbene (NHC) ligand precursors. The symmetrically saturated imidazolium salt prepared by ring closure of achiral tetradentate diquinolyl-diamine with triethyl orthoformate is a tridentate ligand and can function as pincer ligand while the two asymmetric imidazolium salts are bidentate and...
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A series of 'dual-functionalised' ionic liquids, comprising imidazolium cations with various functionalities and the nitrile functionalised anion [CH3CH(BF3)CH2CN]- have been prepared; some exhibit very low viscosities-a highly valuable property in many applications.
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Meysam Yarie was born in 1987 in Malayer/ Hamedan, Iran. He received his B.Sc. in Applied Chemistry from Malek-Ashtar University of Technology and M.Sc. in Organic Chemistry from Kurdistan University under the supervision of Dr. Kamal Amani. He received his Ph.D. from Bu-Ali Sina University under the supervision of Professor Mohammad Ali Zolfigol. He is currently working towards his Post-Doctor...
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Weakly coordinating anions (WCAs) have been a subject of intensive research in the past decades due to their increasing importance in coordination chemistry and catalysis [1 – 6]. These applications have grown out of basic research into the special properties of anions containing hydrocarbon and fluorocarbon functionality such as [SO3CF3], [B(C6F5)4], [OTeF5] [7]. Owing to the importance of WCA...
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We report the extension of the series of {BIPMH} (BIPM = C{PPh2NR}2, TMS = trimethylsilyl) derived rare earth methanides by the preparation of [Ln(BIPMH)(I)2(THF)] (Ln = Nd, Gd, Tb), 1a–c, in 34–50% crystalline yields via the reaction of [Ln(I)3(THF)3.5] with [Cs(BIPMH)]. Similarly, we have extended the range of {BIPMH} (Mes = 2,4,6-trimethylphenyl) derived rare earth methanides with the prepar...
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ژورنال
عنوان ژورنال: Bayero Journal of Pure and Applied Sciences
سال: 2011
ISSN: 2006-6996,2006-6996
DOI: 10.4314/bajopas.v2i2.63766